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論文

Development of secondary ion mass spectroscopy using medium energy C$$_{60}$$ ion impact

平田 浩一*; 齋藤 勇一; 千葉 敦也; 阿達 正浩*; 山田 圭介; 鳴海 一雅

Nuclear Instruments and Methods in Physics Research B, 266(10), p.2450 - 2452, 2008/05

 被引用回数:13 パーセンタイル:64.46(Instruments & Instrumentation)

Time-of-flight (TOF) secondary ion mass spectroscopy was performed using primary C$$_{60}$$ ions with an energy range from several tens of keV to several hundreds of keV. Application of the spectroscopy to the analysis of a poly(amino acid) film revealed that characteristic peaks, necessary for identification of the amino acid in proteins, show higher intensities for medium energy C$$_{60}$$ (120 keV C$$_{60}^{+}$$ and 540 keV C$$_{60}^{2+}$$) impacts than those for low energy C$$_{60}$$ (30 keV C$$_{60}^{+}$$) impacts. This finding demonstrates that medium energy C$$_{60}$$ ion impacts are useful for highly sensitive characterization of amino acids.

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